Selenium The Element of The Millennium


 


General Information
 
 



How to say Selenium
Selenium can be prepared with either an amorphous or crystalline structure.
Crystalline monoclinic selenium is deep red; crystalline hexagonal selenium,
the most stable variety, is a metallic gray. Elemental selenium is relatively
nontoxic and is considered to be an essential trace element. However,
hydrogen selenide (H2Se) and other selenium compounds are extremely toxic,
and resemble arsenic in their physiological reactions. Hydrogen selenide in a
concentration of 1.5 ppm is intolerable to man. Selenium occurs in some soils
in amounts sufficient to produce serious effects on animals feeding on plants
such as locoweed (an American plant) grown in such soils.


 






Atomic Information
 
 



Periodic Table

 Atomic Number: 34
Atomic Mass: 78.96
Electronic Configuration: (Ar)3d104s2p4
Melting Point: 217.0 °C
Boiling Point: 684.9 °C
Density @ 293 K: 4.79 g/cm3


 




Isotopes:

Isotope Half-life Spin Parity Decay Mode(s) or Abundance
65Se  EC+B+=100, ECP=?
66Se  0+
67Se  60 ms EC+B+=100, ECP=0.5
68Se  35.5 s 0+ EC+B+=100
69Se  27.4 s (3/2-) EC+B+=100, ECP=0.045
70Se  41.1 m 0+ EC+B+=100
71Se  4.74 m 3/2-,5/2- EC+B+=100
72Se  8.40 d 0+ EC=100
73Se  7.15 h 9/2+ EC+B+=100
73m1Se  39.8 m 3/2- EC+B+=27.4, IT=72.6
74Se  stable 0+ Abundance=0.89
75Se  119.779 d 5/2+ EC=100
76Se  stable 0+ Abundance=9.36
77Se  stable 1/2- Abundance=7.63
77m1Se  17.36 s 7/2+ IT=100
78Se  stable 0+ Abundance=23.78
79Se  1.13e6 y 7/2+ B-=100
79m1Se  3.92 m 1/2- IT=99.944, B-=0.056
80Se  stable 0+ Abundance=49.61
81Se  18.45 m 1/2- B-=100
81m1Se  57.28 m 7/2+ IT=99.948, B-=0.052
82Se  1.08e+20 y 0+ Abundance=8.73, BB=100
83Se  22.3 m 9/2+ B-=100
83m1Se  70.1 s 1/2- B-=100
84Se  3.1 m 0+ B-=100
85Se  31.7 s (5/2+) B-=100
86Se  15.3 s 0+ B-=100
87Se  5.29 s (5/2+) B-=100, B-N=0.36
88Se  1.53 s 0+ B-=100, B-N=0.99
89Se  0.41 s (5/2+) B-=100, B-N=7.8
90Se 
91Se  0.27 s B-=100, B-N=21
92Se  0+

 

Ions:

Valence Ionization Potential (eV)
-2
0
+1 9.752
+2 21.19
+3 30.82
+4 42.944
+5 68.3
+6 81.7

Radii of Selenium atoms and ions in various coordination's:
IonRadii/Se.gif


 


Elemental Forms:
 


Alloys:
Photoelectric cells (Cd-Se)
Television cameras
Electrostatic copier and Laser printer drums

Sources:
Byproduct of Copper, Lead, and Zinc production
Uranium roll-front deposits


 










Uses of Selenium

Nature's Way logo
 
 


Nature's Way Selenium Each capsule provides provides 200 mcg of Elemental Selenium (selenomethionine). Also contains cellulose, magnesium stearate, silica, and maltodextrin.  Selenium aids Phase III enzyme detoxification of peroxide free radicals; Potentiates the antioxidant activities of other antioxidants; Cardio protective agent; Co-factor with sulfur in amino acid metabolism. Nature's Way Selenomethionine is the organically bound, bioactive form of selenium. Selenium is an essential component of glutathione a potent antioxidant and member of the antioxidant "recycling team." When glutathione is present, vitamin E and vitamin C are recycled into active free radical scavenging forms. Nature's Way yeast-free selenomehionine is a 100% natural, advanced chelated form of selenium with superior absorption


 


            Dangers of Selenium 
 


Selenium and its compounds, particularly selenium dioxide and hydrogen selenide, can cause eye irritation. Inhalation of selenium dust, a concentrated mist of selenium, selenium dioxide or hydrogen selenide, can irritate the nose, throat and
bronchial tubes and cause headaches, dizziness and malaise. Exposure to high concentrations of selenium dioxide can cause bronchial spasms, symptoms of asphyxiation and bronchitis.  Ingestion of high doses of selenium compounds can cause pulmonary edema and lung lesions. Acute oral doses of selenium compounds can cause aches and pains, irritability, chills and tremors. Both acute inhalation of and acute oral exposure to selenium compounds cause respiratory distress. Repeated exposure to selenium can cause metallic taste, a garlic odor to the breath, fatigue, irrita-bility, depression and pallor.Repeated exposure to selenium compounds in food can cause dental cavities and loss of nails and hair. Repeated higher exposures to selenium also may cause liver damage. Inhalation of selenium, selenium dioxide and hydrogen selenide can cause indigestion and nausea. Most studies have not found a link between selenium and cancer; there are no studies available about the reproductive effects of selenium. It is not known if selenium causes lung damage. In industrial uses, electronics and photography account for 46% of selenium use; glass industry, 27%; pigments, 14%;
miscellaneous, 13%.


 






History & Folklore:

Discovered: 1817 , By: Jons Berzelius
                        Origin of Name: From the Greek word SelÍnÍ (Moon)
 

Selenium is an essential trace element which cannot be manufactured by our bodies.
Its named after "Selene" the goddess of the moon.  In 1979 scientists discovered
Selenium's importance to humans.  Selenium is thought to be a powerful antioxidant,
50-100 times more potent than Vitamin E.  Natural sources of Selenium include:
broccoli, tomatoes, tuna, onions, whole-wheat, bran and wheat germ.   Selenium is
also thought to play a role in eyesight, liver function, heart health, and, hair and skin
health.  Common supplement ranges between 50mcg and 200mcg.   Selenium can
be toxic at high doses and should never be taken in excess of 450mcg without a
doctors supervision.


Compounds

                          FSeSeF
                                         name: selenium (I) fluoride
                                         formula weight: 195.917
                                         formal oxidation number of Se: 1
                                         electronic configuration of Se: [Ar].3d10.4s2.4p3

                          Se2Cl2
                                         name: selenium (I) chloride
                                         formula weight: 228.825
                                         formal oxidation number of Se: 1
                                         electronic configuration of Se: [Ar].3d10.4s2.4p3

                          SeBr
                                         name: selenium (I) bromide
                                         formula weight: 158.864
                                         formal oxidation number of Se: 1
                                         electronic configuration of Se: [Ar].3d10.4s2.4p3

                          SeO2
                                         name: selenium (IV) oxide
                                         formula weight: 110.959
                                         formal oxidation number of Se: 4
                                         electronic configuration of Se: [Ar].3d10.4s2

                          H2Se
                                         name: hydrogen (I) selenide
                                         formula weight: 80.976
                                         formal oxidation number of Se: -2
                                         electronic configuration of Se: [Ar].3d10.4s2.4p6
 

Reactions

Selenium has similar chemical properties to Sulphur.

Links

Periodic Table Game