Selenium The Element of The Millennium
General Information
How
to say Selenium
Selenium can be prepared with either an amorphous or
crystalline structure.
Crystalline monoclinic selenium is deep red; crystalline
hexagonal selenium,
the most stable variety, is a metallic gray. Elemental
selenium is relatively
nontoxic and is considered to be an essential trace element.
However,
hydrogen selenide (H2Se) and other selenium compounds
are extremely toxic,
and resemble arsenic in their physiological reactions.
Hydrogen selenide in a
concentration of 1.5 ppm is intolerable to man. Selenium
occurs in some soils
in amounts sufficient to produce serious effects on animals
feeding on plants
such as locoweed (an American plant) grown in such soils.
Atomic Information
Atomic Number: 34
Atomic Mass: 78.96
Electronic Configuration: (Ar)3d104s2p4
Melting Point: 217.0 °C
Boiling Point: 684.9 °C
Density @ 293 K: 4.79 g/cm3
Isotopes:
| Isotope | Half-life | Spin Parity | Decay Mode(s) or Abundance |
|---|---|---|---|
| 65Se | EC+B+=100, ECP=? | ||
| 66Se | 0+ | ||
| 67Se | 60 ms | EC+B+=100, ECP=0.5 | |
| 68Se | 35.5 s | 0+ | EC+B+=100 |
| 69Se | 27.4 s | (3/2-) | EC+B+=100, ECP=0.045 |
| 70Se | 41.1 m | 0+ | EC+B+=100 |
| 71Se | 4.74 m | 3/2-,5/2- | EC+B+=100 |
| 72Se | 8.40 d | 0+ | EC=100 |
| 73Se | 7.15 h | 9/2+ | EC+B+=100 |
| 73m1Se | 39.8 m | 3/2- | EC+B+=27.4, IT=72.6 |
| 74Se | stable | 0+ | Abundance=0.89 |
| 75Se | 119.779 d | 5/2+ | EC=100 |
| 76Se | stable | 0+ | Abundance=9.36 |
| 77Se | stable | 1/2- | Abundance=7.63 |
| 77m1Se | 17.36 s | 7/2+ | IT=100 |
| 78Se | stable | 0+ | Abundance=23.78 |
| 79Se | 1.13e6 y | 7/2+ | B-=100 |
| 79m1Se | 3.92 m | 1/2- | IT=99.944, B-=0.056 |
| 80Se | stable | 0+ | Abundance=49.61 |
| 81Se | 18.45 m | 1/2- | B-=100 |
| 81m1Se | 57.28 m | 7/2+ | IT=99.948, B-=0.052 |
| 82Se | 1.08e+20 y | 0+ | Abundance=8.73, BB=100 |
| 83Se | 22.3 m | 9/2+ | B-=100 |
| 83m1Se | 70.1 s | 1/2- | B-=100 |
| 84Se | 3.1 m | 0+ | B-=100 |
| 85Se | 31.7 s | (5/2+) | B-=100 |
| 86Se | 15.3 s | 0+ | B-=100 |
| 87Se | 5.29 s | (5/2+) | B-=100, B-N=0.36 |
| 88Se | 1.53 s | 0+ | B-=100, B-N=0.99 |
| 89Se | 0.41 s | (5/2+) | B-=100, B-N=7.8 |
| 90Se | |||
| 91Se | 0.27 s | B-=100, B-N=21 | |
| 92Se | 0+ |
Ions:
| Valence | Ionization Potential (eV) |
| -2 | |
| 0 | |
| +1 | 9.752 |
| +2 | 21.19 |
| +3 | 30.82 |
| +4 | 42.944 |
| +5 | 68.3 |
| +6 | 81.7 |
Radii of Selenium atoms and ions in various coordination's:

Elemental Forms:
Alloys:
Photoelectric cells (Cd-Se)
Television cameras
Electrostatic copier and Laser printer drums
Sources:
Byproduct of Copper, Lead, and Zinc production
Uranium roll-front deposits
Uses of Selenium
Each capsule provides provides 200 mcg of Elemental Selenium (selenomethionine).
Also contains cellulose, magnesium stearate, silica, and maltodextrin.
Selenium aids Phase III enzyme detoxification of peroxide free radicals;
Potentiates the antioxidant activities of other antioxidants; Cardio protective
agent; Co-factor with sulfur in amino acid metabolism. Nature's Way Selenomethionine
is the organically bound, bioactive form of selenium. Selenium is an essential
component of glutathione a potent antioxidant and member of the antioxidant
"recycling team." When glutathione is present, vitamin E and vitamin C
are recycled into active free radical scavenging forms. Nature's Way yeast-free
selenomehionine is a 100% natural, advanced chelated form of selenium with
superior absorption
Dangers
of Selenium
Selenium and its compounds, particularly selenium
dioxide and hydrogen selenide, can cause eye irritation. Inhalation of
selenium dust, a concentrated mist of selenium, selenium dioxide or hydrogen
selenide, can irritate the nose, throat and
bronchial tubes and cause headaches, dizziness
and malaise. Exposure to high concentrations of selenium dioxide can cause
bronchial spasms, symptoms of asphyxiation and bronchitis. Ingestion
of high doses of selenium compounds can cause pulmonary edema and lung
lesions. Acute oral doses of selenium compounds can cause aches and pains,
irritability, chills and tremors. Both acute inhalation of and acute oral
exposure to selenium compounds cause respiratory distress. Repeated exposure
to selenium can cause metallic taste, a garlic odor to the breath, fatigue,
irrita-bility, depression and pallor.Repeated exposure to selenium compounds
in food can cause dental cavities and loss of nails and hair. Repeated
higher exposures to selenium also may cause liver damage. Inhalation of
selenium, selenium dioxide and hydrogen selenide can cause indigestion
and nausea. Most studies have not found a link between selenium and cancer;
there are no studies available about the reproductive effects of selenium.
It is not known if selenium causes lung damage. In industrial uses, electronics
and photography account for 46% of selenium use; glass industry, 27%; pigments,
14%;
miscellaneous, 13%.
History & Folklore:
Discovered: 1817 , By: Jons Berzelius
Origin of Name: From the Greek word SelÍnÍ (Moon)
Selenium is an essential trace element which cannot be manufactured by our bodies.
Its named after "Selene" the goddess of the moon. In 1979 scientists discovered
Selenium's importance to humans. Selenium is thought to be a powerful antioxidant,
50-100 times more potent than Vitamin E. Natural sources of Selenium include:
broccoli, tomatoes, tuna, onions, whole-wheat, bran and wheat germ. Selenium is
also thought to play a role in eyesight, liver function, heart health, and, hair and skin
health. Common supplement ranges between 50mcg and 200mcg. Selenium can
be toxic at high doses and should never be taken in excess of 450mcg without a
doctors supervision.
Compounds
FSeSeF
name: selenium (I) fluoride
formula weight: 195.917
formal oxidation number of Se: 1
electronic configuration of Se: [Ar].3d10.4s2.4p3
Se2Cl2
name: selenium (I) chloride
formula weight: 228.825
formal oxidation number of Se: 1
electronic configuration of Se: [Ar].3d10.4s2.4p3
SeBr
name: selenium (I) bromide
formula weight: 158.864
formal oxidation number of Se: 1
electronic configuration of Se: [Ar].3d10.4s2.4p3
SeO2
name: selenium (IV) oxide
formula weight: 110.959
formal oxidation number of Se: 4
electronic configuration of Se: [Ar].3d10.4s2
H2Se
name: hydrogen (I) selenide
formula weight: 80.976
formal oxidation number of Se: -2
electronic configuration of Se: [Ar].3d10.4s2.4p6
Reactions
Selenium has similar chemical properties to Sulphur.
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